【摘要】 用红外透射率分析方法研究了氧化镍薄膜在原始、致色和消色状态的红外透射率光谱，用Ｘ－射线衍射方法测量了在ＫＯＨ和ＬｉＣｌＯ４－ＰＣ电解液中致色和消色时，氧化镍多晶薄膜在（１１１）和（２００）方向衍射峰位的移动，分析了注入离子种类和离子注入位置，认为在ＫＯＨ电解液中致色时，注入离子为ＯＨ－，离子的注入位置在晶粒的间界。在ＬｉＣｌＯ４－ＰＣ电解液中，Ｌｉ＋离子的注入位置同样在晶粒的间界更多还原

【Abstract】 In this paper,infrared transmittance characteristics of nickel oxide film is as-deposited,colored and bleached states were studied with infrared spectroscopy.Diffractional peak shift in the (111) and (200) directions of nickel oxide crystallites was analysed with X-ray diffraction when the films were colored and bleached in KOH and LiClO4-PC electrolyte.Ions and their injected position in the films were discussed,results showed that the injected ions were OH- when the films were colored in KOH electrolyte,the injected position was in the interface of crystallites.The injected Li+ ions were also in the interface of crystallites when the films was bleached in LiClO4-PC electrolyte.更多还原