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水基金属有机物分解法制备Ba0.5Sr0.5TiO3薄膜的研究

Preparation of Ba0.5Sr0.5TiO3 Thin Film by MOD MethodUsing Hydrate Precursor Solution

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【作者】 何夕云丁爱丽仇萍荪罗维根

【Author】 HE Xiyun,DING Aili,QIU Pingsun,LUO Weigen Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai,200050,China

【机构】 中国科学院上海硅酸盐研究所

【摘要】 制备了水基Ba2+、Sr2+、Ti4+三元有机物溶液。根据红外光谱测定及对比实验分析了溶液配制过程中化学反应机理。采用金属有机物分解法(MOD)制备Ba0.5Sr0.5TiO3(BST)薄膜。通过XRD、SEM、TEM、电子衍射及阻抗分析仪等分析测试手段,研究薄膜的相结构、微观形态及电性能。结果表明,所制备BST薄膜呈现纯钙钛矿晶相结构,结晶完整,晶粒小(10~50nm),显微结构均匀致密,并具有良好的电性能(电容密度为160nF/cm2,薄膜厚度400nm)。

【Abstract】 A ternary hydrate precursor solution of Ba2+,Sr2+,Ti4+ was synthesized for preparing barium strontium titanate thin film,Ba0.5Sr0.5TiO3 (BST). The chemical reactions in the solution were investigated by IR analysis and related experiments.The phase structure and microstructure of BST thin film were examined by XRD,SEM,TEM and electric diffraction.The electric properties of BST thin film were studied by resistant analysis method.The BST thin film fabricated from the hydrate precursor solution exhibits pure perovskite phase,fine crystal (1050nm),uniform microstructure and good electric properties (capacitance density is 160nF/cm2 while thickness of the thin film is 400nm.

【关键词】 水基前驱物溶液BST薄膜MOD法
【Key words】 hydrate precursor solutionBST thin filmMOD method
  • 【文献出处】 功能材料 ,JOURNAL OF FUNCTIONAL MATERIALS , 编辑部邮箱 ,1999年04期
  • 【分类号】TB43
  • 【被引频次】2
  • 【下载频次】70
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