【摘要】 酞菁类化合物作为一类有机功能材料，如导体或半导体、气敏元件、电化学催化剂、电致变色及光致变色材料、光动力疗法的药物以及非线性光学材料等［１］，已经受到化学家和材料学家们的关注．近几十年来，化学家们已经成功地合成出了带各种不同取代基和含有不同中心金属原...更多还原

【Abstract】 Novel soluble phenyltri(2,2dimethylpropoxy)subphthalocyaninatoboron and phenyl tri(tertbutyl)subnaphthalocyaninatoboron were prepared in this paper, and their spectral and aggregation properties were also studied. Our results indicate that the maximum absorption wavelength of SubNc is about 80 nm higher than that of SubPc, but both of them are blueshifted about 100 nm compared with corresponding phthalocyanine and naphthalocyanine. Also, we find out that SubPc is stable, but SubNc is unstable to light. In addition, no aggregation in their solution takes place since the great spatialhindrance from the axial phenyl ring precludes molecular aggregation.更多还原