节点文献

表面光接枝原理、方法及应用前景

Principle, Process and Application of Surface Photografting Polymerization

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 杨万泰尹梅贞邓建元杜久明

【Author】 Yang Wantai, Yin Meizhen, Deng Jianyuan, Du Jiuming (Beijing University of Chemical Technology, Beijing 100029)

【机构】 北京化工大学材料科学与工程学院

【摘要】 介绍了表面光接枝的原理、方法和应用前景。表面光接枝主要是用芳酮引发有机材料产生表面自由基,从而引发单体聚合生成表面接枝链。实施方法有气相法、液相法和连续液相法。表面光接枝应用领域广泛,可用于聚合材料的表面改性以及表面功能化。

【Abstract】 Surface photografting polymerization (SPGP) may be intiated by the photoredution reation of an aromatic ketone with a surface H donors, the chain transfer of a free radical to the surface of organic materials, as well as the fragmentation of a special photo sensitive group on the surface of materials. SPGP may be conducted by a vapor phase process, a liquid phase process or a bulk phase process. The previous applications of SPGP are surface modification of organic materials, especially polyolefins. The main properties modified by SPGP are adhesiveness, printability, paintability, dyeability, anti fogging properties, gloss, anti static properties, lubrication, anti staining properties, bio compatibility, heat sealability, and so on. In recent years, extensive researches have been reported for the functionalization of a polymer surface, e.g., the preparation of separation membrane, polymer supported catalysts, reagents, ligands for absorption of metal ions, as well as polymer forming method.

  • 【文献出处】 高分子通报 ,POLYMER BULLETIN , 编辑部邮箱 ,1999年01期
  • 【分类号】TQ316.343
  • 【被引频次】127
  • 【下载频次】1177
节点文献中: 

本文链接的文献网络图示:

本文的引文网络