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催化剂对脉冲放电转化CO2为CO的影响
The Research on Conversion of CO2 to CO by a Pulsed Discharse Plasma with Catalyst
【摘要】 分析研究了催化剂对脉冲放电等离子体作用下,CO2;转化为CO的规律。由于催化剂载体对CO2有一定的吸附能力,在其表面形成CO2富积区;而且催化剂表面为场强加强区,更易发生化学反应,因此催化剂存在时,CO的产生量几乎不受CO2含量的影响;而无催化剂情况下,CO2含量对CO的生成有较大影响。当有O2存在时,有无催化剂情况下,CO生成量都随O2含量的增加而减少,尤其是O2含量从零刚开始增加时;无催化剂情况下CO生成量受O2含量影响较大。
【Abstract】 The conversion of CO2 to CO in atmosphericpressure with cataiyst by a pulsed discharge plasma hasbeen disscused in this paper. The results show that the con-centration of CO2 has almost no influence on gencration ofCO when catalyst exists; but in contrast, the concentrationof CO2 has larger effect on generation of CO without cata-lyst. With or without catalyse, the concentration of COproduced by pulsed discharge decreases with the increase ofthe concentration of O2. The influence of O2 without cata-lyst is more larger than with catalyst. The explanations ofthe results are based on the absorption of CO2 on the surfaceof catalyst and there is a more intensive electric field on thesurface of catalpst.
- 【文献出处】 高电压技术 ,HIGH VOLTAGE ENGINEERING , 编辑部邮箱 ,1999年04期
- 【分类号】TM8
- 【被引频次】10
- 【下载频次】81