【摘要】 合成了配合物［Ｅｕ２Ｃ４０Ｈ４６Ｎ６Ｏ８·２（ＮＯ）３］．配体为邻香兰素与二乙烯三胺缩合而成的双席夫碱．配合物的晶体为单斜晶系，空间群Ｐ２１／ｃ，ａ＝１．６５４６（３）ｎｍ，ｂ＝１．６５１９（３）ｎｍ，ｃ＝１．５８０７（３）ｎｍ，β＝９１．８１（３）°，Ｖ＝４．３１８（２）ｎｍ３，Ｄｘ＝１．７９５Ｍｇ·ｍ－３，Ｚ＝４，μ＝２．９５５７ｍｍ－１，Ｆ（０００）＝２３２０，Ｒ＝０．０５８，Ｒｗ＝０．０７６．Ｅｕ（Ⅲ）的配位数为８，配位几何为双帽三角棱柱．配位原子为氧原子和氮原子更多还原

【Abstract】 The title complex was prepared and characterized by Xray diffraction. The Ligand is dischiff base from ovanillin and diethylenetriamine. The complex crystallizes in monoclinic system, space P21/c, a=\{1.6546(3) nm\}, b=\{1.6519(3) nm\}, c=\{1.5807(3) nm\}, =91\^81(3), V=\{4.318(2) nm3\}, Dx=\{1.795Mgm-3\}, z=4, =\{2.9557mm-1 \}, F(000)=\{2 320\}, the final R=0.058, Rw=0.076. In the complex the coordination number of Eu() is 8 with a geometry of bicapped trigonal prism. The coordination atoms are oxygen atoms and nitrogen atoms.更多还原