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In[（C₂H₅O）₂PS₂]₃配合物的合成及晶体结构研究

Synthesis and Crystal Structure of In 3

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【Author】 LIU XingZhi*, XUE Hong, ZHAO Jin, SONG YuLin, ZANG ShuLiang (Research Institute of Rare and Scatter Elements, Liaoning University, Shenyang, 110036)

【机构】辽宁大学稀散元素化学研究所；

【摘要】稀散元素材料已成为当代高新技术领域的重要支撑材料，其中铟应用于液晶材料（ＩＴＯ）的研究与开发［１，２］．烷基二硫代磷酸酯具有优良的配位性能，可用作石油添加剂和高聚物防老化剂［３，４］．因此，目前对稀散元素烷基硫代配合物研究十分活跃．为进一步研究稀散元...更多还原

【Abstract】 The complex In 3 was synthesised and characterized by IR, MS, TGDTA and elementary analysis. The crystal structure was determined and indicated that In 3 is monoclinic, space group C2/c with a=0816 0(2) nm, b=1878 5(4) nm, c=1792 9(4) nm, ==9000(0), =9215(3), V=2986(1) nm3, Z=4, Dx=1538 g/cm3, F(000)=1 360. The structure was refined to R=0059 and Rw=0063. There are four chemical units in each crystal cell in which In() ion coordinates with six sulfur atoms and the number of coordination is 6. The molecular contiguration of crystal is octahedral.更多还原