【摘要】 用水热法首次合成了含有２ 种有机胺的新型笼状钼磷超分子化合物〔ＮＨ３（ＣＨ２）６ＮＨ３〕７〔ＮＨ３（ＣＨ２）２ＮＨ３〕２（Ｈ３Ｏ）６〔Ｐ２ Ｍｏ５Ｏ２３〕４·１１Ｈ２Ｏ，并通过元素分析、红外和Ｘ－ 射线单晶衍射法进行了结构表征．晶体属三斜晶系，空间群ｐ１杂多阴离子中的每个〔Ｐ２Ｍｏ５Ｏ２３〕６－ 是由５ 个ＭｏＯ６ 八面体和两个ＰＯ４ 四面体键合而成，其中Ｍｏ，Ｐ原子成一个畸变五角双锥构型．更多还原

【Abstract】 A novel cage-shaped molybdophosphate supermolecular compound,〔NH 3(CH 2) 6NH 3〕 7〔NH 3(CH 2) 2NH 3〕 2(H 3O) 6〔P 2Mo 5O 23 〕 4·11H 2O has been synthesized by hydrothermal method and characterized by elemental analysis,IR spectrum,and singel crystal x-ray structure analysis.The crystals are triclinic with space group p1,The result of structure analysis shows that each of the four 〔P 2Mo 5O 23 〕 6- of the heteropoly anion consists of five MoO 6 octahedra and two PO 4 tetrahedron,and Mo,P atoms in each of the four 〔P 2Mo 5O 23 〕 6- structures show a distored pentagonal bipyramidal configuration.更多还原