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临界胶束浓度前阳离子表面活性剂诱导激基缔合物形成的荧光光谱研究
Fluorescence Studies of the Excimer Formation Induced by Cationic Surfactant Below the Critical Micelle Concentration
【摘要】 研究了阳离子表面活性剂CTAB在临界胶束浓度(CMC) 前对1 - 芘丁酸(PBA) 和1 - 萘乙酸(NAA) 荧光光谱的影响, 观测到PBA和NAA激基缔合物的发光. 实验证明: CMC前CTAB 能够诱导PBA, NAA激基缔合物的形成. 这一结果为设计阴离子表面活性剂的荧光检测新方法提供了理论基础.
【Abstract】 The effect of cationic surfactant CTAB on the fluorescece of 1-pyrenebutyric acid and 1-Naphthylacetic acid was studied below the CMC of CTAB.The excimer emission of PBA and NAA was observed.It was concluded that the cationic surfactant,CTAB at concentration below its CMC could induce the formation of PBA and NAA excimer.This result forms the basis for the sensing assay of anionic surfactant by fluorescence spectroscopy.
【关键词】 胶束;
表面活性剂;
激基缔合物;
荧光光谱;
【Key words】 micelle; cationic surfactant; excimer; fluorescence spectroscopy;
【Key words】 micelle; cationic surfactant; excimer; fluorescence spectroscopy;
【基金】 国家自然科学基金!(29675018);福建省自然科学基金!(D991002)
- 【文献出处】 福州大学学报(自然科学版) ,JOURNAL OF FUZHOU UNIVERSITY(NATURAL SCIENCES EDTION) , 编辑部邮箱 ,1999年S1期
- 【分类号】O657.3
- 【被引频次】5
- 【下载频次】221