【摘要】 在以水溶性铑－膦配合物为催化剂的烯烃氢甲酰化反应中，铑的存在形态及配位结构对烯烃氢甲酰化反应的转化率及选择性起着决定性的作用．在反应过程中，特别是工业生产过程中，会由于各种原因导致一些杂质进入反应体系，这些杂质可能会影响铑－膦配合物催化剂的性质，改变...更多还原

【Abstract】 Effect of some metal cations on 1hexene hydroformylation was investigated. The order of their influence is Na+<K+<Li+<Zn2+<Mg2+< Ca2+ Ni2+< Fe2+< Sr2+< Cu2+< Fe3+< Al3+< Cr3+. The results suggested that the higher the charge of metal ion in the solution, the larger the influence, that is ,the lower the reaction rate. Transition metal ions would influence the interface structure of micelle. Two opposite influence factors, the micelle solubilization and the saltingout effect, were observed in the reaction.更多还原