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镉试剂2B改性硅胶富集和测定水体中的镉

Enrichment and Determination of Trace Cadmium in Waterwith Cadion 2B on Silica Gel

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【作者】 吕鉴泉吕桂英王金鸣

【Author】 Lu Jianquan, Lu Guiying, Wang Jinming(Department of Chemstry,Hubei Normal University,Huangshi,435002)

【机构】 湖北师范学院化学系

【摘要】 报道了用镉试剂2B改性的硅胶(Cadion2B-SG)来富集水体中的痕量镉的各种条件。结果表明,在pH=6的条件下,Cd2+能被Cadion2B-SG定量吸附,其净吸附量为7.9μmolg-1,吸附的Cd2+可被0.1molL-1的HCl洗脱。据此,建立了Cadion2B-SG柱富集、胶束增溶分光光度法测定镉的方法,并对废水中的镉进行了测定,结果令人满意。

【Abstract】 Nitronaphthalenedizoaminoazobenzene(Cadion 2B)on silica gel is used for rapid enrichment of gL-1 level of Cadmium()from aqueous solution,followed by spectrophotometric detemination. Cadmium()was quantitatively retained on the Cadion 2BSG from solution at pH=6 after shaking over 30 minutes.The net absorption capacity of the Cadion 2B on SG is 7.9mol Cd2+g-1.Cadmium retained on the Cadion 2BSG column was completely eluted with 10 mL solution of 0.1 molL-1HCl. Based on these, a spectrophotometric method for determination of cadmium in water is developed. The Cadmium concentration in water is shown to be gL-1 level.

【关键词】 镉试剂2B改性硅胶富集
【Key words】 Cadion 2BSilica gelEnrichmentCadmium
  • 【文献出处】 分析科学学报 ,JOURNAL OF ANALYTICAL SCIENCE , 编辑部邮箱 ,1999年02期
  • 【分类号】O614.242
  • 【被引频次】7
  • 【下载频次】97
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