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小波变换用于电位滴定法测定极弱酸

Application of Wavelet Transform Method in Potentiometric Titration of Very Weak Acids

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【作者】 司圣柱; 王丽平; 王洪; 印春生;

【Author】 Si Shengzhu , Wang Liping (Department of Chemistry, Anhui Institute of Education, Hefei 230061)Wang Hong (Supreme Pmcuratarate of P.R. China, Beijing 100039)Yin Chunsheng (Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026)

【机构】 安徽教育学院化学系; 中华人民共和国最高人民检察院; 中国科学技术大学应用化学系 合肥230061; 合肥230061; 北京100039; 合肥230026;

【摘要】 研究了用小波变换确定电位滴定终点方法测定硼酸和苯酚两种极弱酸,同经典方法及其它数学方法的结果进行比较,说明用小波变换电位滴定法测定极弱酸快速、准确,可为极弱酸的计算机联机测定提供一种新的途径.

【Abstract】 A novel method for finding of end points of acid-base potentiometric titration by using wavelet transform strategy was developed to determination of amount of very weak acids of orthoboric acid and phenol. The comparison of the results obtained by proposed method and the conventional methods or rational spline function method showed that the wavelet transform technique in combined with potentiometric titration method for determination of very weak acid has the advantage of rapidity and accuracy. It may provide a new way for automatic titration of very weak acids using potentiometer with computer.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1999年08期
  • 【分类号】O657.1
  • 【被引频次】14
  • 【下载频次】89
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