【摘要】 提出了一种测定Fenton反应产生羟自由基的偶合化学发光分析法.羟自由基与苯甲酸发生羟化反应后生成的羟基苯甲酸能增大钌(Ⅱ)邻菲咯啉-Ce(Ⅳ)化学发光反应的发光强度.用化学发光法测定羟基苯甲酸的含量可间接测定自由基的生成量.拟定的方法,简单、灵敏度高,可用于筛选羟自由基消除剂.更多还原

【Abstract】 A new chemiluminescent method for determination of hydroxyl,radicals from Fenton reaction was proposed, besed on die hydroxyl radicals reacting with benzoic acid to produce hydroxyl benzoic acidwhich enhanced chermiluminescence emission of Ru ( phen)2+ -Ce (Ⅳ) . The quantitative analysis ofhydroxyl radicals can be done through the chemiluminescent mehtod for determination of hydroxyl benzoic acid. The method proposed is sensitive, simple and accurate for the selection of hydroxyl radicals scavengers.更多还原