【摘要】 对黄沙坪铅锌矿床内带铁闪锌矿的研究表明，其形成温度为３００℃±；压力大致为１０７Ｐａ；成矿溶液为中偏酸性，硫逸度较高，还原性较强。成矿溶液中Ｆｅ和Ｚｎ的主要配合物有：ＦｅＣｌ＋、ＦｅＯＨ＋、ＦｅＣｌ０、Ｚｎ（ＨＳ）０２、ＺｎＣｌ＋、ＺｎＣｌ０２、Ｆｅ２＋等。Ｆｅ２＋主要是铁闪锌矿结晶过程中进入八面体位置的，这是ＺｎＳ与ＦｅＳ之间构成有限固溶体的根本原因。更多还原

【Abstract】 The marmatite in the inner zone of the Huangshanping Pb-Zn deposit was deposited from weak acid solution with higher sulfuric fugacity and strong redution at 300℃ and 10 7 Pa. The main complexes of Fe and Zn are FeCl +, FeOH +, FeCl 0, ZnCl 0 2, ZnCl +, Zn(HS) 0 2, FeCl 0 2, Fe 2+ ,etc. Because of Zn-Fe limited solid solution, the Fe 2+ entered the octahedral sites of marmatite from solution when marmatite crystallized.更多还原