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制备工艺对球形氢氧化镍结构和性能的影响
Studies of the effects of preparation process on the structure and performance of spherical nickel hydroxide
【摘要】 通过XRD、Raman光谱和电化学实验表明,反应液的pH值、NH3的用量以及不同的添加剂,对氢氧化镍的晶粒大小、结晶性好坏和微结构缺陷等有重要的影响。在实验中确定了反应的最佳工艺,使氢氧化镍的堆积密度>2.1g/cm3,放电比容量>270mAh/g。
【Abstract】 It is shown by X ray diffraction,Raman spectroscopy and electrochemical tests, that the properties of nickel hydroxide such as the crystallite size,the degree of crystallinity and the structure defects,are strongly effected by the pH value,ratio of NH 3 and NaOH,and special additives.The nickel hydroxide with tap density>2.1g/cm 3 and discharge capacity>270mAh/g is prepared by the most efficient process which was determined by many experiments.
【关键词】 球形氢氧化镍;
制备工艺;
晶粒度;
结晶性;
比容量;
【Key words】 spherical nickel hydroxide; preparation process; crystallite size; degree of crystallinity; specific capacity;
【Key words】 spherical nickel hydroxide; preparation process; crystallite size; degree of crystallinity; specific capacity;
【基金】 国家“863”计划资助
- 【文献出处】 电源技术 ,CHINESE JOURNAL OF POWER SOURCES , 编辑部邮箱 ,1999年S1期
- 【分类号】TM912.2
- 【被引频次】30
- 【下载频次】377