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氧化环境中预暴露对IC-6合金高温拉伸性能的影响

EFFECTS OF PRE-EXPOSURE ON THE TENSILE PROPERTIES OF DIRECTIONALLY SOLIDIFIED IC-6 ALLOYS AT HIGH TEMPERATURE

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【作者】 袁福河周龙江李铁藩陈江

【Author】 YUAN Fuhe; ZHOU Longjiang; LI Tiefan; CHEN Jiang (State Key Laboratory of Corrosion and Protection of Metals, Institute of Corrosion and Protection of Metals, The Chinese Academy of Sciences, Shenyang 110015)(To whom correspondence should be addressed)

【机构】 中国科学院金属腐蚀与防护研究所金属腐蚀与防护国家重点实验室

【摘要】 为了解IC-6合金在高温氧化环境中的力学损伤行为.研究了900、1000、1100℃空气中预暴露100h后合金的组织变化和拉伸性能.合金在预暴露后强度变化不大。且在不高于1000℃下预暴露后合金拉伸塑性没有受到氧化损伤.与K17G镍基合金相比,IC-6合金所具有的这些明显优势被归因于定向凝固方法消除了横向晶界、抑制了空气中的氧沿晶扩散所造成的高温氧化环境的力学损伤.在1100℃预暴露后.由于在合金表面生成挥发性MoO3,合金基体沿枝晶间严重氧化,合金强度急剧下降.

【Abstract】 To understand the damage effects produced by hostile oxidizing environments on the mechanical properties of Ni3Al-Mo base IC-6 alloys. the present work concentrates on the changes in microstructure and attendant degradation in the tensile properties of IC-6 alloys at 850℃ in air following air pre-exposure treatments at 900, 1000 and 1100℃ for 100h. The strength of IC-6 alloy does not drop substantially and when exposed not in excess of 1000℃. ductility loss in IC-6 alloy was not observed as opposed to K17G nickel base superalloys. The excellent resistance of IC-6 alloys to environmental damage derives as unidirectional solidification technology successively eliminates the transverse grain boundaries, thereby precludes the mechanical loss occurrence effected by oxidizing environments as a result of oxygen inward diffusion along the otherwise existing grain boundaries. Preexposure at 1100℃ results in brittle fracture in IC-6 alloy by virtue of volatile MoO3 formation in oxide film and accompanying oxidizing attack deep into the interdendritical regions.

【基金】 国家自然科学基金!59771066
  • 【文献出处】 材料研究学报 ,CHINESE JOURNAL OF MATERIAL RESEARCH , 编辑部邮箱 ,1999年01期
  • 【分类号】TG14
  • 【下载频次】53
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