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碳酸根离子柱撑钴铝水滑石的合成与表征

THE SYNTHESIS AND CHARACTERIZATION OF CARBONATEPILLARED CoAl HYDROTALCITELIKE COMPOUND

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【作者】 肖轶马骏任韶玲杨锡尧

【Author】 Xiao Yi, Ma Jun, Ren Shaoling, Yang Xiyao (Catalysis Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871)

【机构】 北京大学化学与分子工程学院催化研究室

【摘要】 水滑石类化合物近年来受到人们的广泛关注,它具有的独特的阴离子柱撑层状结构及独特的阴离子可交换性和阳离子可搭配性,使它成为一种多功能的新型催化材料[1].本文报道的是钴铝水滑石类化合物(CoAlHT)的制备规律及其表征.1实验部分1.1CoAl?..

【Abstract】 Various preparative factors such as precipitation method, operational temperature, pH value and Co/Al molar ratio, which affect the purity and crystal form of CoAl hydrotalcitelike compound were studied. The results of product characterization by XRD and FTIR methods show that low supersaturation coprecipitation at constant pH, which handling at 6070, pH ranging from 8 to 115 and Co/Al molar ratio ranging from 2 to 35, give rise to high purity and better crystal form of CoAl hydrotalcitelike compounds.

【基金】 国家科委专项基金
  • 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,1999年04期
  • 【分类号】O643
  • 【被引频次】125
  • 【下载频次】553
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