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微量铈对Ni P非晶态合金催化剂的苯加氢性能及热稳定性的影响

EFFECT OF CERIUM ADDITION UPON THE ACTIVITY AND THE THERMOSTABILITY OF ULTRAFINE AMORPHOUS Ni P ALLOY CATALYSTS FOR BENZENE HYDROGENATION

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【作者】 陈昌荣卞国柱姜明万小红李忠瑞韦世强

【Author】 Chen Changrong 1, Bian Guozhu 1, Jiang Ming 1, Wan Xiaohong 2, Li Zhongrui 1, Wei Shiqiang 2,3 (1 Department of Chemical Physics; 2 National Synchrotron Radiation Laboratory; 3 Center for Fundamental Physics, University of Science and Technol

【机构】 中国科学技术大学!化学物理系合肥230026中国科学技术大学!国家同步辐射实验室中国科学技术大学!国家同步辐射实验室中国科学技术大学基础物理中心

【摘要】 采用化学还原法制备了不同铈含量的NiPCe 超细非晶态合金催化剂,测试了其苯加氢活性. 应用X 射线衍射和差热方法对经不同温度退火后的样品进行了结构分析,并和其苯加氢活性相关联. 实验发现,微量铈的加入可大大提高催化剂的热稳定性,进而提高其加氢活性.

【Abstract】 The thermal stability of ultrafine Ni P Ce amorphous alloy catalysts with different cerium contents prepared by chemical reduction method and annealed at different temperatures in a flow of argon was studied by X ray diffraction and differential thermal analysis. Benzene hydrogenation was used as a test reaction of the catalytic properties of the annealed samples. It is found that the activity of the samples strongly depends upon the amorphous structure of the Ni P alloys. The addition of small amount of cerium to the samples significantly enhances the thermal stability of the amorphous structure and thus the activity for benzene hydrogenation.

【基金】 国家自然科学基金
  • 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,1999年06期
  • 【分类号】O643
  • 【被引频次】43
  • 【下载频次】160
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