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Pt-Sn/MgAl2O4催化剂的TPR和H2-TPD研究

TPR AND H 2 TPD STUDIES OF Pt Sn/MgAl 2O 4 CATALYSTS

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【作者】 董文生; 王心葵; 王浩静; 彭少逸;

【Author】 Dong Wensheng, Wang Xinkui, Wang Haojing, Peng Shaoyi (Shanxi Institute of Coal Chemistry, The Chinese Academy of Sciences, Taiyuan 030001)

【机构】 中国科学院山西煤炭化学研究所!太原030001;

【Abstract】 Pt Sn/MgAl 2O 4 catalysts prepared by co impregnation with nominal 0 35% platinum and varying content of tin (0~2 5%) were characterized by temperature programmed reduction (TPR) and temperature programmed desorption of hydrogen (H 2 TPD). TPR results showed that platinum catalyzed the reduction of tin. However, the average oxidation state of tin after reduction depended upon the concentration of tin on the catalysts. H 2 TPD data indicated that tin addition inhibited the inactivated adsorption of hydrogen but promoted the activated adsorption, implying that tin modified both the ensembles of platinum and metal support interface, thus increasing hydrogen mobility and promoting hydrogen spillover.

  • 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,1999年05期
  • 【分类号】O643
  • 【被引频次】22
  • 【下载频次】689
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