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载钛中孔二氧化硅分子筛的光催化性能
STUDY ON PHOTOCATALYTIC PERFORMANICE OF TITANIA SUPPORTED ON MESOPOROUS SILICA MOLECULAR SIEVE
【摘要】 分别 以单一 Ti O2 纳米粒 子及不 同 Ti O2 覆 盖率的中 孔分 子筛( Ti O2/ H M S) 和微 孔分 子筛( Ti O2/ Na Y) 为光催 化剂,以2 ,4 ,6三氯苯 酚( T C P) 为 降解对象 ,考察了 两类分子 筛担 载 Ti O2 的光催化性 能. 结 果表明 : 在钛 含量相 同的 条 件下 , Ti O2/ H M S 的光 催 化活 性 高于 Ti O2/ Na Y 和 单一 Ti O2 的光催 化活性; Ti O2 负载量 较低时 , Ti O2/ H M S 即可 显示 有高 的光 催化 活性, 且其 光催 化活性随着 中孔分 子筛孔径 的增大而 升高
【Abstract】 The photocatalytic performance of titania supported on hexagonal mesoporous silica (HMS) and zeolite Y (NaY) for degradation of 2,4,6 trichlorophenol (TCP) was investigated. It was found that the photocatalytic activity of TiO 2/HMS was higher than that of TiO 2 powder itself and TiO 2/NaY. It was also found that the TiO 2 /HMS had higher photocatalytic activity at lower Ti content. The larger the pore size of HMS used as the support is, the higher the photocatalytic activity of TiO 2 for the degradation of TCP is. These results suggest that the support structure is a main factor responsible for the enhancement of photocatalytic activity of TiO 2.
【Key words】 nanoparticle; titania; silica; mesoporous molecular sieve; zeolite Y; photocatalysis; trichlorophenol;
- 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,1999年03期
- 【被引频次】77
- 【下载频次】373