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臭氧紫外法处理TNT水溶液的研究

Ozone Ultraviolet Oxidative Treatment of TNT in Water

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【作者】 欧阳吉庭; 刘晓春; 冯长根; 陈海燕; 梁宇文;

【Author】 Ouyang Jiting Liu Xiaochun Feng Changgen Chen Haiyan Liang Yuwen (1 Department of Applied Physics, Beijing Institute of Technology, Beijing100081; 2 Department of Engineering Safety, Beijing Institute of Technology, Beijing100081; 3 Research Center

【机构】 北京理工大学应用物理系!北京100081; 北京理工大学机电工程系!北京100081; 北京理工大学机电工程系!北京10008; 中国工程物理研究院环境保护工程研究中心!成都610003;

【摘要】 目的 研究梯恩梯(TNT)水溶液在臭氧紫外氧化工艺下的降解特性方法 通过实验,测定不同氧化条件下TNT降解过程中的TNT、三硝基化合物、臭氧等相关物质的浓度变化结果与结论 单独臭氧氧化对TNT的降解作用小;臭氧紫外联合氧化作用对TNT降解效果明显;碱性环境对臭氧紫外氧化法降解TNT的促进作用不大经臭氧紫外氧化处理后,TNT水溶液中仍残存一定量的三硝基化合物,当其质量分数下降到25以后变化非常缓慢从经济角度出发,臭氧紫外氧化法不适合于TNT水溶液的深度处理

【Abstract】 Aim To study the degradation of TNT in water by ozone ultraviolet advanced oxidation process (O 3+UV). Methods The concentration changes of various compounds such as TNT, trinitroaromatic compounds, O 3, etc. were investigated by experiments. Results and Conclusion TNT can be degraded more faster by combining O 3 with UV radiation while very slowly by only using O 3. A high pH does not improve the removal efficiency of O 3+UV process significantly. There still exist some trinitroaromatic compounds in the solution after TNT being processed, and they will reduce slowly after the mass fraction is less than 25%. The O 3+UV process is not suitable for the final treatment of trinitroaromatic compounds.

【基金】 中国工程物理研究院院外科学技术基金!资助项目 ( 970 5 38)
  • 【文献出处】 北京理工大学学报 ,JOURNAL OF BEIJING INSTITUTE OF TECHNOLOGY , 编辑部邮箱 ,1999年05期
  • 【分类号】X78
  • 【被引频次】29
  • 【下载频次】330
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