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高聚物的低温动态力学性能

Dynamic Mechanical Performance of Some Polymers at Low Temperature

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【作者】 秦亚萍刘子如孔扬辉阴翠梅张沛

【Author】 QIN Ya ping,LIU Zi ru,KONG Yang hui (Xi′an Modern Chemistry Research Institute,Xi′an 710065,China)

【机构】 西安近代化学研究所

【摘要】 用DMA(动态机械热分析仪)研究了几种高聚物的低温动态力学性能,测定了样品的动态力学性能参数,并且应用动态力学性能的TTS(时温叠加)原理,求得了WLF方程的常数C1和C2,由C1和C2进一步计算出材料的脆性参数,同时从分子结构角度解释了本文所研究试样之间贮能模量和脆性参数的差别。

【Abstract】 In this paper, the dynamic mechanical performance of some polymers was investigated by DMA. The parameters of dynamic mechanical performance of samples were determined. Base on the time temperature superposition principle of dynamic mechanical performence, constants C 1 and C 2 of WLF equation were obtained, and the fragility parameters of samples were calculated form C 1 and C 2. The differences of storage modulus and fragility parameter of samples were explained form the point of view of molecular structure.

  • 【文献出处】 火炸药学报 ,CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS , 编辑部邮箱 ,1999年02期
  • 【分类号】O631.21
  • 【被引频次】27
  • 【下载频次】464
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