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ZnO导电陶瓷的制备及其性能表征

Preparation of ZnO Conductive Ceramics and Its Properties

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【作者】 林元华; 张中太; 袁方利; 李晋林;

【Author】 Lin Yuanhua, Zhang Zhongtai(Material Science and Engineer Department, Tsinghua University, Beijing\ 100084)Yuan Fangli, Li Jinlin(Institute of Chemical Metallurgy, The Chinese Academy of Sciences, Beijing\ 100080)Received 1 November 1998, revised manuscr

【机构】 清华大学材料科学与工程系!北京100084; 中国科学院化工冶金研究所!北京100080;

【摘要】 本文利用化学共沉淀法分别制得Zn5(CO3)2(OH)6 掺杂Al(OH)3、Mg(OH)2 以及Zn5(CO3)2(OH)6 掺杂Sb(OH)3、Bi(OH)3、Sn(OH)4、Co(OH)3、MnO(OH)2 两种复合粉体,利用高频等离子体焙解新工艺,制得了纳米ZnO 及相应的添加剂陶瓷复合粉体.TEM 分析结果表明:两种陶瓷复合粉体的粒径均小于100nm .利用前者,通过添加适当的Al2O3 和MgO,制备出了电阻率约10~2000Ω·cm ,V-I特性较好的ZnO 线性陶瓷电阻.利用后者,通过适当的杂质配比,在1000℃左右烧结,可获得致密的瓷体,压敏电压可达480V/m m 左右,非线性系数可达52.

【Abstract】 In this paper,two kinds of composite powders (Zn\-5(CO\-3)\-2(OH)\-6+Al(OH)\-3+Mg(OH)\-2 and Zn\-5(CO\-3)\-2(OH)\-6+Sb(OH)\-3+Bi(OH)\-3+Sn(OH)\-4+Co(OH)\-3+MnO(OH)\-2) have been prepared respectively by the chemical coprecipitation method. The new calcined technology adopted high frequency plasma is used to prepare nanometer ZnO ceramic powders with correspond additives.The analytical results of TEM proved that particle sizes of both kinds of composite powders are below 100nm. Adding some amount of Al\-2O\-3 and MgO in ZnO ceramics, the ZnO linear ceramic resistor with resistivity of 10~2000Ω·cm is prepared, which had good V\|I characteristic.The compressed ceramic body is made by calcining the second composite powder at 1000℃ 2h,the sensitive potential may reach 480V/mm and nonlinear coefficient may be 52.

  • 【文献出处】 半导体学报 ,CHINESE JOURNAL OF SEMICONDUCTORS , 编辑部邮箱 ,1999年10期
  • 【分类号】TN304.21
  • 【被引频次】35
  • 【下载频次】745
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