【作者】 颜静； 张雪； 李学装； 张秋禹； 闫毅；

【Author】 Jing Yan;Xue Zhang;Xuezhuang Li;Qiuyu Zhang;Yi Yan;Department of Applied Chemistry, School of Science, Northwestern Polytechnical University;

【机构】 西北工业大学理学院；

【摘要】 有机金属高分子(Metallopolymers),尤其是金属基团为可电离基团的有机金属聚电解质(Metallopolyelectrolyte)近年来受到了广泛的关注1-2。在这类杂化分子中,金属基元赋予了其丰富的功能特性,超分子/高分子的机械性能和自组装性质使得这类分子的加工和实际使用成为可能3,4。金属基构筑基元的选择对这类杂化分子的制备和性能至关重要5。本报告中,将介绍我们以有机修饰的多金属氧簇、二茂钴鎓离子为金属基构筑基元,通过沉淀聚合、加聚等方法构筑杂化聚合物方面的研究进展,重点介绍这类杂化材料的构筑方法、自组装行为及其在选择性吸附分离和缓蚀方面的应用。更多还原

【Abstract】 Metallopolymers, especially metal-based organometallic polyelectrolytes(Metallopolyelectrolytes) with ionizable groups, have received extensive attention in recent years. Metal elements endow these hybrid molecules with abundant functional properties. The mechanical properties and self-assembly properties of supramolecular/macromolecule make it possible for the processing and practical use of these molecules. The selection of metal-based building units is crucial for the preparation and properties of these hybrid molecules. In this report, we will introduce our research progress in the construction of hybrid polymers based on organically modified polyoxometalate clusters and cobaltoceniums. We will focus on the preparation, self-assembly behavior and applications in selective adsorption and separation as well as corrosion inhibition of these hybrid materials.更多还原