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基于银的导电网络结构构筑及研究

Preparation and Study of Free-standing Conductive Silver Mesh

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【作者】 王晓露赵宁徐坚

【Author】 Xiaolu Wang;Ning Zhao;Jian Xu;Beijing National Laboratory for Molecular Science, Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences;

【机构】 中国科学院化学研究所高分子物理与化学实验室

【摘要】 本文通过微流体纺丝法实现了微米银线及独立导电银网[1,2]的制备。首先以粘度较高的聚N-乙烯基吡咯烷酮为纺丝材料,以硝酸银为银的前驱体,丙烯酸酯树脂作为光固化材料,实现了银纳米颗粒的原位生成,制备了不依赖于基底的独立的导电银网。研究表明持续激光照射诱导硝酸银的还原以及丝线表面致密银层的形成。测试表明银网方阻最小可达0.2?sq-1

【Abstract】 In this work, the preparations of micron silver fibers and free-standing silver mesh1,2 were achieved taking advantage of the microfludic spinning technique. In the experiment, aqueous solution of poly(N-vinylpyrrolidone) was employed as the spinning material due to its high viscosity. At the same time, silver nitrate acted as the silver precursor while the acrylate resin was used as the photopolymerized monomer. It was indicated that the continuous-wave laser induced the photoreduction of silver ions and closedly packed silver nanoparticles were formed at the surface of the fiber. The minimum sheet resistance was measured to be 0.2 ? sq-1.

【关键词】 微流体纺丝导电银网
【Key words】 microfludic spinningconductive silver mesh
  • 【会议录名称】 第十一届全国高聚物分子与结构表征学术研讨会会议论文集
  • 【会议名称】第十一届全国高聚物分子与结构表征学术研讨会
  • 【会议时间】2018-10-17
  • 【会议地点】中国湖北武汉
  • 【分类号】O614.122;TB383.1
  • 【主办单位】中国化学会
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