【作者】 赵新；

【Author】 Xin Zhao;Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences;

【机构】 中国科学院上海有机化学研究所；

【摘要】 本报告将介绍我们近期发展的两类新型晶态二维多孔聚合物:异孔共价有机框架(Heteropore Covalent Organic Frameworks, Heteropore COFs)和超分子有机框架(Supramolecular Organic Frameworks,SOFs)。基于单体结构的理性设计,利用动态共价键或主客体作用驱动的成键方式,构筑了一系列不同拓扑结构的二维多孔聚合物,这些多孔聚合物具有高度长程有序的周期性结构,表现出作为功能材料的良好应用潜力如气体吸附,有害物质捕获,以及荧光检测等。更多还原

【Abstract】 This presentation will focus on two emerging classes of crystalline two-dimensional(2D) porous organic polymers: Heteropore Covalent Organic Frameworks(Heteropore COFs) and Supramolecular Organic Frameworks(SOFs). On the basis of the rational structural designs of the monomers, a series of 2D porous organic polymers with different topological structures have been constructed by using dynamic covalent bonds or host-guest interactions as the linkages. These porous polymers possess high long-range internal orders and exhibit great potentials to be functional materials for gas absorption, capture of hazard substances, and fluorescent sensing.更多还原