Photo-Induced Glycosylation Reactions

【作者】 叶新山；

【Author】 Xin-Shan Ye;State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University;

【机构】 北京大学；

【摘要】 <正>Glycosylation is unarguably the most important reaction in the field of glycochemistry.However,only a handful of photo-induced glycosylations have been reported.Since the activation of glycosyl donors largely depends on the redox potential of a photosensitizer or photocatalyst,the existing methods require a careful adjustment of anomeric leaving groups to ensure a successful light-induced activation,and exhibit an extremely更多还原