【作者】 张刊； 白跃峰； 赵可清； 余文浩； 倪海亮； 汪必琴； 胡平；

【Author】 Kan Zhang;Yue-Feng Bai;Ke-Qing Zhao;Wen-Hao Yu;Hai-Liang Ni;Bi-Qin Wang;Ping Hu;College of Chemistry and Materials Science, Sichuan Normal University;

【机构】 四川师范大学；

【摘要】 点击反应由于简单、高效、适用范围广泛等特点,使其作为一种合成方法广泛应用于材料学、生物医学等领域。目前,将点击反应生成的三唑五元环作为功能基元或官能团的相关研究还相对较少。本文以苯并菲为盘状介晶基元,通过端炔与高能叠氮点击反应生成1,4-二取代,1,2,3-三唑五元环桥连的苯并菲二聚体,再以其为母体,通过与氯化钯配位形成苯并菲液晶超分子化合物1,以及与含端基羧酸的苯并菲化合物通过室温挥发的方法得到氢键复合物2a~d。FTIR检测发现:氢键作用的超分子化合物2中,存在单氢键和双氢键两种氢键作用;当含端基羧酸的单体与二聚体的比例增加至3:1时,分子间氢键的数目不再增加。两类超分子化合物的介晶性质通过DSC和POM的检测,均表现出较好的介晶性特征,特别是配位键作用的超分子化合物1相对点击反应生成的二聚体的介晶区间拓宽了70℃,为可逆复变六方柱状相。更多还原

【Abstract】 Click reaction as an efficient tool is widely used in the field of materials science, biology and medicine as for the simple and high efficient properties. However, the triazoles which are generated by the click reaction are used as a functional group is relatively few. In this manuscript, we have synthesized the triphenylene discotic liquid crystal dimmer from terminal alkyle and by copper(I) catalyst at firstly. Then, the triazole was treated as an electron donor with palladium chloride or carboxylic acid derivative to form two kinds of superamoleculars compounds. All the superamolecular compounds exhibited well ordered hexagonal columnar mesophases.更多还原