【作者】 罗小龙； 王冬梅； 王爽； 霍启升； 刘云凌；

【Author】 Xiaolong Luo;Dongmei Wang;Shuang Wang;Qisheng Huo;Yunling Liu;State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University;

【机构】 吉林大学无机合成与制备化学国家重点实验室；

【摘要】 类分子筛配位聚合物由于具有与传统沸石分子筛相类似的拓扑结构、大孔道或孔穴展现出许多优异之处,然而这类材料的设计合成仍然是一个极具挑战性的难题[1-3]。最近,我们运用分子构筑块法、超分子构筑块法、金属簇结构基元等多种设计合成策略,成功组装了系列新型类沸石结构的多孔配位聚合物,如由氢键构筑的类分子筛超分子化合物及具有单一手性和螺旋孔道的类分子筛配位聚合物[4-5]。更多还原

【Abstract】 Recently,zeolite-like metal-organic frameworks(ZMOFs),as s subclass of MOFs which are hybrid organic-inorganic porous solids resemble inorganic zeolites in their topologies,offers the potential to construct porous solids with extra-large cavities via decoration and/or expansion of a given zeolite net.We have successful assembled of a series of ZMOFs materials by utilizing molecular building blocks,supramolecular building blocks,metal-cluster building units strategies etc,including zeolite-like supramolecular assemblies via H-bond and a chiral ZMOF with helical channels.更多还原