【作者】 张羽飞； 李智敏； 卢加添； 曹小平； 周克勋； Dietmar Kuck；

【Author】 Yu-Fei Zhang;Zhi-Min Li;Jia-Tian Lu;Xiao-Ping Cao;Hak-Fun Chow;Dietmar Kuck;State Key Laboratory of Applied Organic Chemistry,College of Chemistry and Chemical Engineering Lanzhou University;Department of Chemistry,The Chinese University of Hong Kong;Department of Chemistry,Bielefeld University;

【机构】 兰州大学功能有机分子化学国家重点实验室化学化工学院； 香港中文大学化学系； Department of Chemistry Bielefeld University；

【摘要】 三苯三戊并烯（tribenzotriquinacene,TBTQ）独特的C₃对称刚性骨架结构及多样的反应活性在有机、材料、主客体识别、超分子等研究领域具有重要意义1,2。我们进行了一系列单翼TBTQ衍生物的研究,通过TBTQ苯炔中间体参与的Diels-Alder反应,合成了TBTQ并蒽等衍生物3。通过IBX氧化反应制备了TBTQ-邻苯醌,由此衍生出一系列TBTQ单翼多官能团化合物,用缩合反应制备了TBTQ并吩嗪类衍生物,并研究了其光物理性质4。由TBTQ-邻苯醌与三蝶烯六胺制备三叶片结构衍生物的研究工作正在进行中。更多还原

【Abstract】 Tribenzotriquinacene(TBTQ) and its derivatives are belonging to a novel and fascinating family of polycyclichydrocarbons.Based on TBTQ monoaryne and monoisobenzofuran,TBTQ-anthracene has become accessible.An IBX oxidation method was used to synthesize novel TBTQ-o-quinones.Rich follow-up chemistry provided new paths to construct single wing extended TBTQ derivatives,such as TBTQ-phenazines,and their photophysical property were also investigated.The research work on the 3-vane wheels of TBTQ-molecular structure is ongoing.更多还原