【作者】 李严严； 苑强涛； 倪天军； 杨志军；

【Author】 Yanyan Li;Qiangtao Yuan;Tianjun Ni;Zhijun Yang;Department of Chemistry, Xinxiang Medical University;

【机构】 新乡医学院化学教研室；

【摘要】 金属有机骨架材料(MOFs)是一类具有广阔应用前景的新型多孔材料。由于其在结构上常具有特殊活性位点、较高且可调的孔隙率、超高的比表面积和化学可修饰等优点,近年来在催化领域中的应用受到人们的广泛关注。本文先设计合成了三角架配体1,3,5-三(1,2,4-三氮唑-1-亚甲基)-2,4,6-三甲基苯,再以此配体与金属铜进行配位,然后通过元素分析、晶体结构测定、粉末衍射、红外分析,热重分析及荧光分析等对该配合物进行了表征。最后通过其对染料的降解效果来研究其在催化降解方面的作用,进而应用到实际生活中去。更多还原

【Abstract】 Metal organic framework material(MOFs) is a new kind of porous material with wide application prospect.Due to the unique structural features and outstanding physical /chemical properties,including metal or organic active sites in pore surface,high/tunable porosity,high specific surface area and the possibility to functionalize,metal organic frameworks(MOFs) as promising catalytic materials have attracted considerable attention in recent decade.In this thesis, first designed and synthesized a tripod ligand 1,3,5-Tris(triazol-1-ylmethyl)-2,4,6-trimethyl benzene, and then the ligand and the metal copper coordination,Then the complex was characterized by elemental analysis, crystal structure determination, powder diffraction, infrared analysis, thermal analysis and fluorescence analysis.Study its role in catalysis degradation through its effect on the degradation of dye, and then applied to real life.更多还原