Construction of Quaternary Stereocenters via Pd-Catalyzed Asymmetric Decarboxylative Cycloaddition

【作者】 张勇健；

【Author】 Zhang Yong Jia;School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University;

【机构】 School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University；

【摘要】 <正>The development of efficient methods for the construction of quaternary stereogenic centers is an important objective in asymmetric catalysis.In this presentation,I will present our recent research results for the construction of quaternary stereogenic centers via palladium-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates(VECs)with unsaturated更多还原