节点文献
A chair-conformation {Ag6}6+ clusters stabilized by {Ag3(Spz)3(NP3)} motifs
【作者】 梁光明; 吴学鹏; 苏畅; 倪青玲; 王修建; 徐美玉;
【机构】 广西师范大学化学与药学学院;
【摘要】 In this paper, ligands of pyrazine-2-thiol(Spz) and tris((diphenyl-phosphino)methyl)amine(NP3) were exploited synergistically to construct a neutral molecule {Ag3(Spz)3(NP3)} which can perform as a tridentate unit to stabilize the cluster cores. The resulted clusters [Ag12(Spz)12(NP3)2][Ag3(Spz)3(NP3)]2?(DMF)6(1) are structurally determined by X-ray diffraction. Complex(1) contains a central chair-conformation [Ag6]6+ ring.
【Abstract】 In this paper, ligands of pyrazine-2-thiol(Spz) and tris((diphenyl-phosphino)methyl)amine(NP3) were exploited synergistically to construct a neutral molecule {Ag3(Spz)3(NP3)} which can perform as a tridentate unit to stabilize the cluster cores. The resulted clusters [Ag12(Spz)12(NP3)2][Ag3(Spz)3(NP3)]2?(DMF)6(1) are structurally determined by X-ray diffraction. Complex(1) contains a central chair-conformation [Ag6]6+ ring.
- 【会议录名称】 2015年中西部地区无机化学化工学术研讨会会议论文集
- 【会议名称】2015年中西部地区无机化学化工学术研讨会
- 【会议时间】2015-04-22
- 【会议地点】中国广西桂林
- 【分类号】O641.4
- 【主办单位】中国化学会、国家自然科学基金委员会