【作者】 唐果东； 张宇； 赵剑英； 张载超；

【Author】 Guodong Tang;Yu Zhang;Jianying Zhao;Zaichao Zhang;Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials,School of Chemistry and Chemical Engineering,Huaiyin Normal University;

【机构】 淮阴师范学院化学化工学院；

【摘要】 合成了配体2-(4-醛基苯基)咪唑[4,5-f]1,10-邻菲罗啉及其配合物。对合成的配体进行了1HNMR表征,并用配体合成了锰的配合物,同时得到了晶体结构,该配合物属于Orthorhombic晶系,Pnna空间群。在此基础上,对配体和配合物做了一系列光学和热稳定性研究。在紫外-可见吸收光谱中,配合物较配体产生红移。配体有良好的荧光发射性能,配合物没有荧光性能。配合物具有三阶非线性光学性能。配合物有较好的热稳定性。更多还原

【Abstract】 The ligand 2-(4-aldehyde group phenyl) imidazole [4,5-f] 1,10-phenanthroline has been synthesized,and was determined by 1HNMR.Meanwhile,the manganese complex was synthesized,the crystal structure was determined by X-ray crystal diffraction,the complex crystal system:Orthorhombic,space group:Pnna.A series of optical and thermal stability were studied about the ligand and complex.About the ultraviolet-visible absorption spectrum,the complex has red shift.Ligand has good fluorescence emission properties,and the complex with no fluorescence properties.But the complex has the third-order nonlinear optical properties.And has good thermal stability.更多还原