【作者】 曹越； 于凯； 苏占华； 周百斌；

【Author】 Yue Cao;Kai Yu;Zhanhua Su;Baibin Zhou;Key Laboratory of Synthesis of Functional Materials and Green Catalysis,Colleges of Heilongjiang Province,Harbin Normal University;

【机构】 哈尔滨师范大学；

【摘要】 用水热法合成了一种基于{PMo12}层的有机无机杂化物[Ag(pz)2]6[PMo12O40]2·3H2O(1)(pz=pyrazol),X-射线单晶衍射分析表明,两个独立的{PMo12}簇和邻近的三个多酸球以AB-AB模式通过超分子作用形成两种不同尺寸的六边形孔洞的二维面,两种层通过[Ag(pz)2]+链进一步形成一种特殊复杂的三维超分子结构。据我们所知,这是第一例包含{PMo12}和pz配体的化合物。此外,化合物1还表现出很好的氧化还原性和荧光性。更多还原

【Abstract】 An organic–inorganic hybrid compound based on {PMo12} layers, [Ag(pz)2]6[PMo12O40]2·3H2O(1)(pz = pyrazol) has been hydrothermally synthesized. Single-crystal X-ray diffraction indicates, two [PMo12O40]3-clusters connect to adjacent three polyoxoanion clusters in AB-AB mode via supramolecular interactions. Two kinds of layer are further connected to form complex 3-D supramolecular network. To the best of our knowledge, this is the first hybrid containing [PMo12O40]3- and the pz ligands up to now. In addition, compound 1 exhibits good electrocatalytic activity and fluorescent properties.更多还原