Cu(0)/Selectfluor System-Mediated One-pot Synthesis of Biaryls from Tertiary Cyclohexanols

【作者】 张家慧； 张巍； 汪衡； 刘运奎；

【Author】 Jia-Hui Zhang;Wei Zhang;Heng Wang;Yun-Kui Liu;

【机构】 浙江工业大学化工学院；

【摘要】 <正>The biaryl scaffold is also an important and frequently occuring structural element in a large number of biologically active natural products and synthetic molecules,polymers,functional materials,and liquid crystals.~1 To date,established methods for the construction of biaryls maily focus on routes of transition metal-catalyzed cross-coupling reactions between an aryl halide and an aryl organometallic reagent.~2 Despite effectiveness,this methodology suffers from the need of更多还原