Synthesis and Reactivity of Triorganostannyl Derivatives of 1,1-Bis(pyridin-2-yl) ethanes

【作者】 杨焕； 尹庚文； 唐良富；

【Author】 Huan Yang;Geng-Wen Yin;Liang-Fu Tang;Department of Chemistry,State Key Laboratory of Elemento-Organic Chemistry,Nankai University;

【机构】 Department of Chemistry,State Key Laboratory of Elemento-Organic Chemistry,Nankai University；

【摘要】 <正>Transition-metal stannyl complexes have been extensively investigated for a long time,due to their important roles in many catalytic transformations.The introduction of a stannyl group can remarkably change the properties of complexes and their catalytic activity.~1 The oxidative addition of the Sn-C bond to the low-valent transition-metal centers is one of the synthetic methods for these complexes.~2 Our recent investigations displayed that the reaction of(triarylstannyl)bis(pyrazol-1-更多还原