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Investigations on the Reactions of Thioureas with Fe3(CO)12
Investigations on the Reactions of Thioureas with Fe3(CO)12
【作者】 石尧成; Shuai Wang;
【Author】 Yao-Cheng Shi;Shuai Wang;
【机构】 扬州大学化学化工学院;
【摘要】 <正>Recently,we have initiated the project developing synthetic methodologies of iron-sulfur cluster complexes.1-4As part of this on-going project,we report herein the syntheses and crystal structures of Fe/S cluster complexes with chelating carbenes.The reaction of ArNHC(=S)NHPh with Fe3(CO)12produces complexes(μ3-S)2Fe3(CO)7(k2N,C-ArNHCNHCPh)(1,Ar=2-C5H4N;2,Ar=2-C4H3N2).Similarly,(2-C5H4N)NHC(=S)NH(2-CH3C6H4)offers complexμ3-S)2Fe3(CO)7(k2N,C-(2-C5H4N)NH-CNH(2-CH3C6H4)(3).However,(2-C5H4N)NHC(=S)NH(2-CH3OC6H4)generates
- 【会议录名称】 第十八届全国金属有机化学学术研讨会论文摘要集
- 【会议名称】第十八届全国金属有机化学学术研讨会
- 【会议时间】2014-08-19
- 【会议地点】中国甘肃兰州
- 【分类号】O627.81
- 【主办单位】中国化学会