Syntheses,crystal structures and electrochemistry of diiron complexes from the reactions of [Et₃NH][（μ-RS）Fe₂（CO）₆（μ-CO）] with EtNCS

【作者】 石尧成； Ying Shi；

【Author】 Yao-Cheng Shi;Ying Shi;

【机构】 扬州大学化学化工学院；

【摘要】 <正>Hydrogen（H₂）is a clean and renewable fuel.Hydrogenase enzymes very efficiently catalyze the reductive generation and oxidative uptake of molecular hydrogen.Enzymes typically feature binuclear active sites:either iron and nickel,[FeNi]hydrogenases or two irons,[Fe-Fe]hydrogenases.However,the large size and relative instability of these enzymes under aerobic conditions has led to the search for well-defined molecular catalysts that can produce hydrogen from water in a nonbiological system.Platinum is an excellent catalyst for proton reduction and更多还原