Free Radical/Carbon Electrophile-Initiated Addition/Semipinacol Reaction of Allylic Silyl Ethers

【作者】 涂永强；

【Author】 Yong-Qiang Tu;

【机构】 兰州大学功能有机分子化学国家重点实验室；

【摘要】 <正>In the field of organic chemistry,pursuing the"ideal synthesis",as one of the evergreen topics,has been stimulating tremendous efforts toward the development of efficient synthetic methodologies.Among them,intermolecular semipinacol rearragements,which could simultaneously achieve the construction of multi-chemical bonds and the reorganization of molecular skeletons,have attracted broad attentions of synthetic chemistry community.^[1]Based on our long term interest in the 1,2-migration reactions,we developed recently free radical/carbon electrophile-initiated addition/semipinacol reaction of allylic silyl更多还原