Iron-Catalyzed Selective Direct Cyanation of Electron-Rich Arenes with a New Cyanating Agent:CBIT

【作者】 舒志斌； 季文治； 张艳； 王剑波；

【机构】 北京大学化学与分子工程学院；

【摘要】 <正>The direct cyanation1,2 of electron-rich arenes has been developed under iron-catalyzed oxidation conditions using a new cyanating agent:CBIT,cyano(3,5-bis(trifluoromethyl)phenyl)iodonium triflate.The procedure has been successfully extended to the direct regioselective cyanation of a wide range of electron-rich aromatic substrates,including polycyclic aromatic and更多还原