Size-controllable heterometallic metal-organic cages

【作者】 李皓； 金国新；

【机构】 复旦大学化学系；

【摘要】 <正>The synthesis of size-controllable heterometallic metal-organic cages(HMOCs)is intriguing,particularly to supramolecular catalysis,because catalysis in HMOC could mimic the enzyme-catalyzed reaction:the cage structure built by the junction of the first metal center gives an inner cavity which could function as the catalytic pocket,whereas the second metal center could function as active sites.1更多还原