【作者】 王琼； 张林军； 张冬梅； 杜姣姣； 贾林；

【Author】 WANG Qiong;ZHANG Linjun;ZHANG Dongmei;DU Jiaojiao;JIA Lin;Xi’an Modern Chemistry Research Institute;

【机构】 西安近代化学研究所；

【摘要】 在前人关于绝热加速量热技术数据分析的基础上,推导出了分别以温度和压力数据计算均相反应体系和固相分解反应表观活化能的模型参数和非模型参数计算方法,给出了推导过程中的假设条件和结果的应用范围。分析了文献关于用绝热加速量热技术研究含能材料相容性方法的适用性,初步提出了新的评价含能材料相容性的评价参数△D。更多还原

【Abstract】 The model-fitting method and model-free method of calculation of apparent activation energy by adiabatic accelerating rate calorimeter for the heterogeneous reaction and solid-state decomposition reaction were obtained based on the work of formers,with pointing out the application premise and applied range for each equation and some flaws of the formers’ results.The applicabiUty of adiabatic accelerating rate calorimeter on evaluating the compatibility of energetic materials was analyzed and the new parameter △D evaluating the compatibility was put forward preliminarily.更多还原