【作者】 张丽鹏； 于先进； 洪淑翠； 董云会； 李德刚； 张欣；

【Author】 ZHANG Li-peng~1 YU Xian-jin~1 HONG Shu-cui~2 DONG Yun-hui~1 LI De-gang~1 ZHANG Xin~1 (1.School of Chemical Engineering,Shandong University of Technology,Zibo 255049,China; 2.Department of Chemical Engineering,Zibo Vocational Institute,Zibo 255000,China)

【机构】 山东理工大学化学工程学院； 淄博职业学院化学工程系；

【摘要】 在高纯氩气气氛下,将 AlCl₃与溴化1-丁基-3-甲基咪唑（BMIM）Br 反应合成透明的铝基离子液体（BMIM）Br- AlCl₃;采用红外光谱仪、扫描电镜及 X 射线能谱仪对其结构进行表征。在298.15 K 下进行16 h 铝电沉积实验, 通过循环伏安曲线法测定其电化学窗口。研究结果表明:铝基离子液体（BMIM）Br-AlCl₃的电化学窗口为3.40 V; 扫描电镜分析表明,阴极新生态的铝晶粒生长完整、晶界完善;X 射线能谱分析阴极表面新生态铝的结果显示主元素为铝,微量元素为氧。更多还原

【Abstract】 An ionic liquid was prepared by mixing AlCl₃ and 1-methyl-3-butylimidazolium bromide （BMIM） under dry argon atmosphere.The structure of （BMIM）Br-AlCl₃ was confirmed by IR.Aluminum electrolysis was conducted at 298.15 K for 16 h by the ionic liquid.The electrochemical window was measured at 298.15 K by cyclic voltammetry. Cathode surface was analyzed by SEM and EDS.The results show that the electrochemical window is 3.40 V,the crystal grain of new deposit aluminum is ideal,and the boundary of crystal grain is perfect.The main element is aluminum and trace element is oxygen on the surface of cathode.更多还原