【作者】 粟智；

【Author】 Su Zhi(Life and Environment Science Institute, Xijiang Normal University, Urumqi 830054, China)

【机构】 新疆师范大学生命与环境科学学院；

【摘要】 基于多相催化反应动力学的特点和基本原理,提出多相催化反应动力学方程的一般形式,并介绍了用Matlab语言设计确定多相催化反应动力学方程参数的通用程序。处理时先对实验测定不同时刻对应的反应速率v₀和浓度C（或压力P）,利用无约束最优化计算方法求出多相催化反应动力学方程参数。文中以镍硅藻土催化苯加氢合成环己烷的实验数据为例进行验证,结果表明,利用所编程序确定的动力学方程和理论值及文献值很好吻合。更多还原

【Abstract】 Based on the characteristics and the theory of heterogeneous catalytic reaction, it persents the method of determining the kinetic equation and parameters of heterogeneous catalytic reaction by designing computer pro gram. During the process, for the measured concentricity value C（or pressure P）and the reactoin rete v₀ in differential time, the unconstrained optimization method is used to get the kinetic parameters. Calculation examplesfor experimental data of the reaction of synthetic cyclohexane with benzene by hydro-conversion at the nickel diatomaceous earth catalyst are given out, the results show a good agreement to the results computed with the theoretical and reference value.更多还原