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铝诱导非晶硅薄膜的场致低温快速晶化
Aluminum-induced Crystallization of Amorphous Silicon (a-Si)
【机构】 汕头大学物理系;
【摘要】 利用铝诱导非晶硅薄膜晶化制备多晶硅薄膜可以降低退火温度,缩短退火时间。在此基础上,通过在退火过程中加入电场加速界面处硅、铝原子间的互扩散,实现了非晶硅薄膜在更低温度下更加快速的晶化。实验结果表明,外加电场,退火温度为400℃退火时间为60min时,薄膜的晶化率接近100%;退火温度为450℃退火时间为30min时,薄膜呈现明显的晶化现象;退火温度为500℃退火时间为15min时,薄膜的X射线多晶峰强度与非晶峰强度之比为未加电场的3~4倍。
【Abstract】 Aluminum-induced crystallization of amorphous silicon (a-Si) is a suitable method for preparation of polycrystalline silicon (poly-Si) films, which can decrease annealing temperature and shorten annealing time. Biasing an electric field, which is perpendicular to the surface of the a-Si films, will accelerate the mutual diffusion of Al atoms and Si atoms on the interface during the aluminum-induced crystallization process and enhance the crystallization of the a-Si films obviously. The experiment results show that without the effect of electric field, a-Si film will not crystallize until the annealing temperature reached 500℃. While under the action of the electric field, almost all of a-Si transfers into poly-Si when the a-Si film was annealed at annealing temperature Ta=400℃ and annealing time ta = 60min; the a-Si films have obviously crystallized at Ta =450℃ and ta=30min; at Ta=500℃ and ta = 15min, the XRD intensity of crystalline silicon (c-Si) components in the films is thrice to fourfold as strong as that in the films without the effect of electric field.
【Key words】 amorphous silicon film polycrystalline silicon film external electric field;
- 【会议录名称】 21世纪太阳能新技术——2003年中国太阳能学会学术年会论文集
- 【会议名称】2003年中国太阳能学会学术年会
- 【会议时间】2003
- 【分类号】TM914.4
- 【主办单位】中国太阳能学会