节点文献
Effect of salt solutions on chain structure of partially hydrolyzed polyacrylamide
【Author】 ZHANG Qing ZHOU Ji-sheng ZHAI Yong-ai LIU Feng-qi GAO Ge College of Chemistry and MacDiarmid Laboratory,Jilin University,Changchun 130021,China
【机构】 College of Chemistry and MacDiarmid Laboratory,Jilin University；
【摘要】 <正>The effect of salt solutions（NaCl,Na2SO4 and CaCl2）on the conformational properties of partially hydrolyzed polyacrylamide（HPAM）was investigated by using static laser light scattering（SLLS）.The special interaction between CaCl2 solution and HPAM was also researched.Experimental results show that the chain structure of HPAM is interrelated with the charge density,the kind and the concentration of salt solutions.The mean-square radius of gyration（Rz）and the second virial coefficient（A2） of HPAM decrease with increasing concentration of salt solutions,and the salt effect tends towards the maximum when the concentration of salt solution is increased to some amount.
【Abstract】 The effect of salt solutions（NaCl,Na2SO4 and CaCl2）on the conformational properties of partially hydrolyzed polyacrylamide（HPAM）was investigated by using static laser light scattering（SLLS）.The special interaction between CaCl2 solution and HPAM was also researched.Experimental results show that the chain structure of HPAM is interrelated with the charge density,the kind and the concentration of salt solutions.The mean-square radius of gyration（Rz）and the second virial coefficient（A2） of HPAM decrease with increasing concentration of salt solutions,and the salt effect tends towards the maximum when the concentration of salt solution is increased to some amount.
- 【会议录名称】 Proceedings of the 9th National Conference on Rheology
- 【会议名称】The 9th National Conference on Rheology
- 【会议时间】2008-09
- 【会议地点】中国湖南长沙
- 【分类号】O633.22
- 【主办单位】Chinese Society of Rheology(CSR)、Central South University of Forestry & Technology(CSUFT)、Xiangtan University(XTU)、Hunan University of Technology(HNUT)