【作者】 王昌权； 边贺东； 于青； 梁宏；

【Author】 Chang-quan wang He-Dong Bian Qing Yu Hong Liang~* College of Chemistry and Chemical Engineering, Guangxi Normal University,Guilin, 541004

【机构】 广西师范大学化学化工学院；

【摘要】 <正>四唑及其衍生物是一类具有重要应用价值和良好生物活性的化合物,因而受到广泛的关注。本文合成了1-甲基-5-巯基四氮唑 Pb(Ⅱ)的配合物并解析了它的晶体结构。配合物属于三斜晶系,空更多还原

【Abstract】 Tetrazole and its derivatives have been focused on because of important application value and favorable bioactivity. In this paper, we present a new complex of Pb（Ⅱ） with 5-mercapto-1-methyltetrazole. The title complex belongs to triclinic system with space group Pī, a = 10.0884（12）（?）, b = 10.6832（14）（?）, c = 12.6198（16）（?）,α = 71.9490（10）⁰,β = 79.0790（10）⁰,γ =84.446（2）⁰, Z = 1, R₁ = 0.0380, wR+2 = 0.0922（I> 2σ（I））. The title complex contains a trinuclear unit with a center of inversion. Six S atoms from six tetrazole ligands coordinate to the Pbl. The 4-N atom of one tetrazole ligand, one water molecule and two N atoms of one 2,2’-bipy ligand coordinate to Pb2.更多还原