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两种新型光应答性有机/无机复合纳米管的合成表征

Organic/Inorganic Composite Nanotubes

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【作者】 童志伟张晓波张田林井上晴夫

【Author】 Zhiwei Tong,* Xiaobo Zhang, Tianlin Zhang, Haruo Inoue School of Chemical Engineering, Huaihai Institute of Technology, Jiangsu, 222005

【机构】 淮海工学院化学工程学院

【摘要】 <正>以MV2+-K4Nb6O17和PrNH3+-H4Nb6O17两种复合物作为前驱体,利用离子交换的方法方法合成了光应答性两种新型有机/无机复合纳米管材料,两种新型有机/无机复合纳米管材料显示非常好的光应答

【Abstract】 We synthesized two types of photoresponsible multilayers spiral nanotubes by the introduction of polyfluorinated cationic azobenzene surfactant into either interlayer I or into both interlayers I and II by a guest-guest exchange method using the intercalation compounds MV2+-K4Nb6O17 and PrNH3+-H4Nb6O17as precursors. The alternatively layered niobate hybrid with the guest species intercalated only into the interlayers of I is referred to as type-A, while the niobate with the guest species intercalated into both interlayers I and II is referred to as type-B. The two types spiral nanotubes exhibited an excellent photoresponse, which could be monitored by measuring UV-vis spectra. The two types of photoresponsible multilayers spiral nanotubes have been characterized by X-ray diffraction, IR, SEM, AFM, TEM.

  • 【会议录名称】 中国化学会第26届学术年会纳米化学分会场论文集
  • 【会议名称】中国化学会第26届学术年会纳米化学分会场
  • 【会议时间】2008-07
  • 【会议地点】中国天津
  • 【分类号】TB383.1
  • 【主办单位】中国化学会
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