【作者】 胡普州； 王建革； 秦建华； 赵邦屯；

【Author】 Pu-Zhou Hu Jian-Ge Wang Jian-HuaQin Bang-Tun Zhao (Department of Chemistry, Luoyang Normal University, Luoyang 471022, P. R. China)

【机构】 洛阳师范学院化学系；

【摘要】 合成了磺化硫桥杯[4]芳烃和钡的配合物,并经X-射线晶体衍射方法确定了其结构。更多还原

【Abstract】 A novel barium(Ⅱ) p-sulfonatothiacalix[4]arene complex has been structurally authenticated by X-ray diffraction studies and reveals that the barium(Ⅱ) ion is coordinated by the oxygen atoms of sulfonato group in thiacalix[4]arene, and also ligated by oxygen atoms of water in crystal lattice, which results in one-dimensional polymer. The further assembly of polymer chain is mediated by aromatic-aromatic interactions in off-set fashion. Finally, a 3-D network is fabricated by synergic hydrogen bonds, π-π and metal-ligand interactions.更多还原